I've found the best way to level alts is Pet Battling over by Halfhill in Pandaria. My Nightborne Priest I got to 90 that way (the rest was WoD Treasures, then regular leveling post 100), my Mag'har Shaman I'm at 61 with 16 hours or so played. Having a second monitor to zone out and watch Netflix or whatever helps. I think it's the fastest way to get to 90 personally. I really dislike the leveling changes so I just Pet Battle now.
Heirlooms are special pieces of armor that level up with your character, so they have stats that are always respectable for your character’s level (up to level 110). Heirlooms that fit the head, shoulder, chest, legs, and back armor slot offer an experience bonus. The total bonus is 45 percent if you have them all. It’s also possible to acquire a ring that adds another 5 percent, but you must win a fishing contest acquire it, and that can take some time.